The Kincasslagh crooner is set to sing a duet with Majella, 49, on RTE’s All Ireland Talent Show.
The loved-up pair are set to bring the house down with the classic Endless Love.
It is believed it will be the first time Daniel and Majella have sung together on television.
Although Daniel is know around the world having sold millions of albums, Majella also has a beautiful voice.
Majella, who married Daniel, also 49, eight years ago, recently released her album by request.
The All Ireland Talent Show is on RTE One at 6.30pm.